3-Aminopropyltriethoxysilane as a promoter in the crosslinking of carboxylated nitrile rubber by surface-oxidized carbon black

Author(s):  
Sumanda Bandyopadhyay ◽  
P. P. De ◽  
D. K. Tripathy ◽  
S. K. De
Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1330 ◽  
Author(s):  
Maria Rosaria Acocella ◽  
Aniello Vittore ◽  
Mario Maggio ◽  
Gaetano Guerra ◽  
Luca Giannini ◽  
...  

Influence of different graphite-based nanofillers on crosslinking reaction of resorcinol, as induced by hexa(methoxymethyl)melamine, is studied. Curing reactions leading from low molecular mass compounds to crosslinked insoluble networks are studied by indirect methods based on Differential Scanning Calorimetry. Reported results show a catalytic activity of graphene oxide (eGO) on this reaction, comparable to that one already described in the literature for curing of benzoxazine. For instance, for an eGO content of 2 wt %, the exothermic crosslinking DSC peak (upon heating at 10 °C/min) shifted 6 °C. More relevantly, oxidized carbon black (oCB) is much more effective as catalyst of the considered curing reaction. In fact, for an oCB content of 2 wt %, the crosslinking DSC peak can be shifted more than 30 °C and a nearly complete crosslinking is already achieved by thermal treatment at 120 °C. The possible origin of the higher catalytic activity of oCB with respect to eGO is discussed.


Carbon ◽  
1998 ◽  
Vol 36 (7-8) ◽  
pp. 1011-1019 ◽  
Author(s):  
F. Coloma ◽  
J. Narciso-Romero ◽  
A. Sepúlveda-Escribano ◽  
F. Rodríguez-Reinoso

2018 ◽  
Vol 8 (1) ◽  
Author(s):  
Kittima Amornwachirabodee ◽  
Nattapol Tantimekin ◽  
Porntip Pan-In ◽  
Tanapat Palaga ◽  
Prompong Pienpinijtham ◽  
...  

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Yaqin Yu ◽  
Xinrui Li ◽  
Jiemin Cheng

The isothermal adsorption kinetics of Cu2+onto Carbon Black (CB) and Oxidized Carbon Black (OCB) were studied under different solution conditions and compared with bentonite and organic bentonite with the hexadecyltrimethylammonium bromide (HDTMA). The adsorption capacities followed the order of OCB > CB > organic bentonite > bentonite, which was consistent with the orders of their surface roughness and specific surface area. The Fourier transmission infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), and transmission electron microscope (TEM) were used to explore the adsorption mechanism at molecular level. The adsorption process onto CB was physical adsorption. However, with the increase of oxygen-containing functional groups (C=O, C-O, and CNO), the chelation adsorption onto OCB became gradually dominant except physical adsorption. The ion exchange adsorption was the major adsorption mechanism of bentonite. The compounds were introduced into clay interlayer by complexing reaction with Cu2+, which improved the adsorption capacity of organic bentonite. The results present a significant implication for the environmental fate assessment of heavy metal pollution.


2005 ◽  
Vol 78 (4) ◽  
pp. 633-635
Author(s):  
S. A. Imankulova ◽  
N. B. Kondrashev ◽  
V. A. Val’tsifer
Keyword(s):  

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Atip Boonbumrung ◽  
Pongdhorn Sae-oui ◽  
Chakrit Sirisinha

The properties of nitrile rubber (NBR) reinforced by multiwalled carbon nanotube (MWCNT), conductive carbon black (CCB), carbon black (CB), and precipitated silica (PSi) were investigated via viscoelastic behavior, bound rubber content, electrical properties, cross-link density, and mechanical properties. The filler content was varied from 0 to 15 phr. MWCNT shows the greatest magnitude of reinforcement considered in terms of tensile strength, modulus, hardness, and abrasion resistance followed by CCB, CB, and PSi. The MWCNT filled system also exhibits extremely high levels of filler network and trapped rubber even at relatively low loading (5 phr) leading to high electrical properties and poor dynamic mechanical properties. Although CCB possesses the highest specific surface area, it gives lower level of filler network than MWCNT and also gives the highest elongation at break among all fillers. Both CB and PSi show comparable degree of reinforcement which is considerably lower than CCB and MWCNT.


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